Hi,
In
Port in a Storm by DauntlessGrace, Spike gets Dalton to help Buffy with her homework and they meet in a cemetery.
Summary: A response to a challenge by Mia Vaan. A young Buffy ends up getting lost in LA and is almost raped. A certain blond vampire ends up coming to her rescue, but can't bring himself to feed off of her. He ends up driving her home and takes off into the night. Buffy is called as the slayer not long after that, and both of them get quite the shock when he shows up in Sunnydale looking for a cure for Drusilla. Starts out pre-series, but the majority of it will be a season 2 setting.