There is definitely some darker Buffy to varying degrees, in the following ones, (I'm sure canon Buffy would count it as 'evil'

). I think all relate to a slayer demon side...
Blood Bound by DreamsofSpike
Early Season Four, immediately after Spike is chipped, Giles finds an ancient ritual that could solve their problem of what to do with the not-so-harmless vampire...but Buffy ends up getting a bit more than she bargained for in the process.Buffy is also stepping more towards a darker nature in...
Normal by Kari Mouke
and very much so in this...
A Not So Gorgeous Mistake by Kari Mouke
Her darkness in this gets broken down eventually, interesting fic bit different...
Black Widow by bogwitch
Dark futurefic. Buffy has been missing for several years. When Spike goes to find her, he's in for a very deep shock.