There is a lot of UST in this fic.
In the Army Now by Im_Bloody_English
Summary: Buffy joins the military and heads off to Basic Training. The Boot Camp experience can be rough enough to endure, but there's something, or rather someone that will make her time spent becoming a soldier ten times worse... a Drill Sergeant sent straight from the bowels of hell that takes an instant dislike to her mere presence, Spike. He's evil, he's mean, he hates her but even worse... he lusts for her.
http://spikeluver.com/SpuffyRealm/viewstory.php?sid=24176