Something like that happens in Dancing in the Moonlight by Holly. Buffy dresses like slutty biker chick named Liz and William is a biker called Will when the Halloween spell happens.
http://dark-solace.org/elysian/viewstory.php?sid=49&warning=NC-17A prophecy unfolds just as a new Slayer arrives in Sunnydale. A cocky, British, platinum blond Slayer with a devilish smile and a body to die for. And Buffy doesn't know what surprises her more—the fact that he's male, or the animal attraction that festers between them almost from the beginning