These fics may be what you're looking for - all a good read regardless.
Something Blue-ish by Lenore
Rated: PG-13
Summary: Challenge # 274 on the Bloodshedverse. "In Season 4's episode "Something Blue" Willow's spell works on Buffy but not on Spike write us a fic of Buffy chasing around a terrified Spike demanding he marry her. To the point that she claims him only seconds before the spell ends :P
http://dark-solace.org/elysian/viewstory.php?sid=1773Something Unexpected by katelyn_d_89
Rated: R
Summary: Set during Something Blue. When Spike decides to make his relationship with Buffy a little more permanent than marriage, huge consequences arise. What will happen to Spike and Buffy's lives once the decision is made?
http://dark-solace.org/elysian/viewstory.php?sid=2408Somethings by Ashlee
Rated: NC-17
Summary: It's never a good idea to claim a Slayer when under the influence...
http://dark-solace.org/elysian/viewstory.php?sid=216Wicked by Holly
Rated: NC-17
Summary: Buffy's choice of Halloween costume might have been whimsical, but she wasn't quite prepared for it to be life-changing.
http://dark-solace.org/elysian/viewstory.php?sid=2727