I probably rec this one quite often, but I just love it that much!

It takes place in Season 4 and (IMO) fits your criteria well.
It All Started With Sex by
Kari MoukeIt all started with sex. Riley did it badly. He knew it. They argued. Supposedly about Angel. Buffy said something she shouldn't. Not being who she was. Not being over a Hellmouth. Poof. Sex. Really, really good sex. NC17. Hard Spuffy. Season four. No Chip. Spike never returned to Sunnydale after Lover's Walk.
Also, posted on Elysian Fields are the
FluffyFiles series by
Hils. These are just some fluffy rewrites of a few episodes (various seasons) where Buffy is accepting of Spike without much angst.